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Persistent carbene
查词链接:
https://www.dute.org/dict/Persistent_carbene
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abstract:
A persistent carbene (also known as stable carbene or Arduengo carbene) is a type of carbene demonstrating particular stability. The best-known examples are diaminocarbenes with the general formula (R2N)2C:, where the 'R's are various functional groups.
网络释义
稳定卡宾
1-金刚烷基是体积较大且稳定的取代基,存在于一些稳定卡宾(Persistent carbene)中。著名的雅各布森(Jacobson)不对称狄尔斯-阿尔德反应催化剂就包含一个金刚烷基。
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